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Chemistry of silica and zeolite-based materials : synthesis, characterization and applications
- Available as
- Online
Details
- Creator
- edited by Abderrazzak Douhal, Masakazu Anpo
- Format
- Books
- Language
- English
- Contributors
- Publication
-
- Amsterdam, Netherlands ; Oxford, England ; Cambridge, Massachusetts : Elsevier, [2019]
- ©2019
- Physical Details
-
- 1 online resource (465 pages)
- ISBNs
- 9780128178140, 9780128178133, 0128178140, 0128178132
- OCLC
- on1107797047
- Includes index.
- Front Cover -- Chemistry of Silica and Zeolite-Based Materials -- Copyright Page -- Contents -- List of Contributors -- About the Editors -- Preface -- 1 Synthesis and Applications of Periodic Mesoporous Organosilicas -- 1.1 Introduction -- 1.2 Synthesis of Periodic Mesoporous Organosilicas -- 1.2.1 Fundamentals of Periodic Mesoporous Organosilica Synthesis -- 1.2.2 Functional Periodic Mesoporous Organosilicas -- 1.2.3 Control of the Arrangement of Organic Moieties in the Pore Walls -- 1.3 Applications -- 1.3.1 Light-Harvesting Antennae -- 1.3.2 Periodic Mesoporous Organosilica-Based Photocatalysis -- 1.3.3 Hole-Transporting Properties and Photovoltaic Devices -- 1.3.4 Substrates for Laser Desorption/Ionization Mass Spectrometry -- 1.3.5 Solid Supports for Metal Complex Catalysts -- 1.3.5.1 Phenylene-Periodic Mesoporous Organosilica -- 1.3.5.2 Phenylpyridin-Periodic Mesoporous Organosilica -- 1.3.5.3 2,2′-Bipyridine-Periodic Mesoporous Organosilica -- 1.3.5.4 Catalysis of Well-Defined Metal Complexes on 2,2′-Bipyridine-Periodic Mesoporous Organosilica -- 1.4 Conclusion and Outlook -- References -- 2 Silica Hosts for Acid and Basic Organosilanes: Preparation, Characterization, and Application in Catalysis -- 2.1 Introduction -- 2.2 Functionalization of Mesoporous Silicas by Organosilanes Containing Acidic Groups -- 2.2.1 Hybrid Materials Containing Strong -SO3H Acidic Centers -- 2.2.1.1 Different Ways for Preparation of Functionalized Materials -- 2.2.1.2 The Role of Additives in Silica Support -- 2.2.1.3 Characterization of Surface Properties -- 2.2.1.4 Application in Catalysis -- 2.2.2 Hybrid Materials Containing Moderate Acidic -PO3H2 and Weak Acidic -COOH Groups -- 2.2.2.1 Preparation and Characterization -- 2.2.2.2 Application in Catalysis -- 2.3 Functionalization of Mesoporous Silicas by Organosilanes Containing Basic Centers
- 2.3.1 Preparation of Mesoporous Silicas Functionalized With Basic Species Containing Nitrogen -- 2.3.2 Characterization of Surface Properties of Hybrid Materials Containing Basic Species -- 2.3.3 Application in Catalysis -- 2.4 Multifunctional Catalysts Based on Amino-Grafted Silica Hybrid Materials -- 2.4.1 Base-BrØnsted Acid Pairs on Silica Surface -- 2.4.2 Base-Lewis Acid Pairs on Silica Surface -- 2.4.3 Base-Redox Pairs on Silica Surface -- 2.4.4 Trifunctional Mesoporous Silica Containing Amine -- 2.5 Transition Metals Anchored on Mesoporous Silicas Functionalized With Organosilanes -- 2.5.1 Location of Organosilane -- 2.5.2 Position of Metal Particles and Metal Dispersion -- 2.5.3 Role of Mature of Functional Group in Organosilane -- 2.6 Concluding Remarks -- Acknowledgments -- References -- 3 Catalytic Interconversion of Sugars with Zeolite and Zeotype Materials -- 3.1 Introduction -- 3.2 Isomerization of Glucose -- 3.2.1 Sn-Modified Zeolite Catalysts -- 3.2.2 Other Zeolite Catalysts -- 3.3 Isomerization of Xylose -- 3.4 Isomerization of Erythrose -- 3.5 Isomerization of Dihydroxyacetone -- 3.5.1 Sn-Beta Zeolite -- 3.5.2 Other Types of Zeolites -- 3.6 Conclusions and Outlook -- Acknowledgments -- References -- Further Reading -- 4 The Microwave-Assisted Synthesis of Silica-Based Materials and Their Photocatalysis -- 4.1 Introduction -- 4.1.1 Electromagnetic Wave and Microwave -- 4.1.2 Different Aspects of Energy and Matter Interactions -- 4.1.3 Basic Principles of Microwave Heating -- 4.1.4 Dielectric Heating -- 4.2 Background of the Porous Materials -- 4.2.1 Silica-Based Materials and Their Synthesis Methods -- 4.2.2 Microwave-Assisted Synthesis Microporous Materials -- 4.2.3 Microwave-Assisted Synthesis of Mesoporous Materials -- 4.3 Effects of Microwave on Silica Materials -- 4.3.1 Stirring, Ramp Rate, and Continuous Process
- 4.3.2 Solvents Dielectric -- 4.3.3 Activation Energy -- 4.3.4 Template -- 4.3.5 Effect of Crystallization -- 4.4 Applications of Silica-Supported Metal Oxides Synthesized by Microwave-Assisted Method in Photocatalysis -- 4.5 Conclusions -- References -- 5 Silica-Based Materials for Photocatalysis -- 5.1 Introduction -- 5.2 Structural Features of Zeolite Photocatalysts -- 5.3 Photocatalytic Process in Zeolites -- 5.4 Applications -- 5.4.1 Pollutant Degradation -- 5.4.2 H2 Production -- 5.4.3 CO2 Reduction -- 5.4.4 Others -- 5.5 Conclusions and Future Perspectives -- Acknowledgments -- References -- 6 Photocatalytic Reactions on Transition Metal-Oxide Single Site Heterogeneous Catalysts Constructed Within Silica-Networks... -- 6.1 Introduction -- 6.2 Titanium-Oxide (Ti-Oxide) Single-Site Heterogeneous Photocatalysts -- 6.2.1 Synthesis of Ti-Oxide Single-Site Photocatalyst Constructed within Zeolite -- 6.2.2 Local Structure of Ti-Oxide Single-Site Photocatalysts -- 6.2.2.1 XAFS Analysis of the Catalysts -- 6.2.2.2 DR UV-Vis Analysis -- 6.2.2.3 Photoluminescence Analysis -- 6.2.2.4 FT-IR Analysis -- 6.2.3 Photocatalytic Reactions on the Highly Dispersed Four-Coordinated Ti-Oxide Single-Site Heterogeneous Catalysts -- 6.2.3.1 Photocatalytic Decomposition of NO -- 6.2.3.2 Photocatalytic Reduction of CO2 with H2O to Form CH4, CH3OH, and O2 -- 6.2.4 Other Transition Metal-Oxides Single-Site Heterogeneous Photocatalysts constructed within Silica Networks of MCM-41 -- 6.2.4.1 Photocatalytic Reduction of N2O with CO on V-Oxide Single-Site Heterogeneous Catalyst -- 6.2.4.2 Selective Photocatalytic Elimination of CO with O2 in H2-Rich Conditions on Mo-Oxide Single-Site Catalysts -- 6.2.4.3 Photocatalytic Selective Elimination of CO with O2 in H2-Rich Condition on Cr-Oxide Single-Site Heterogeneous Catal... -- 6.3 Conclusion -- References
- 7 Silica-Supported Immobilized Amine for CO2 Capture Processes: Molecular Insight by In Situ Infrared Spectroscopy -- 7.1 Introduction -- 7.1.1 Global Carbon Dioxide Emission -- 7.1.2 Postcombustion CO2 Capture Technology -- 7.2 SiO2 and Its Surface -OH/H2Os -- 7.2.1 Properties of SiO2 -- 7.2.2 SiO2-Supported Immobilized Amine Sorbents -- 7.2.3 Probing CO2 Diffusion by the Kinetics of Benzene Adsorption/Desorption -- 7.3 Effects of Liquid H2O on Sorbent Stability -- 7.4 The Molecular Structure of SiO2-Immobilized Amine Sorbents by Vibrational Spectroscopy -- 7.5 CO2 Adsorption/Desorption on SiO2-Supported Amine-Functionalized Sorbents -- 7.6 Degradation of Solid Amine Sorbents -- 7.7 CO2 Capture Process for Solid Amine Sorbents -- 7.8 Conclusions -- Notes -- Acknowledgment -- References -- 8 Silica-Based Catalysts for Fuel Applications -- 8.1 Introduction -- 8.2 SiC Structure and Manufacture -- 8.3 β-SiC Key Properties and Applications -- 8.4 β-SiC Catalytic Support for Fuel Production -- 8.4.1 Reforming Process -- 8.5 Steam Reforming -- 8.6 Dry Reforming -- 8.7 Tri-Reforming -- 8.7.1 Liquid Fuel Production by Fischer-Tropsch Synthesis -- 8.7.2 Production of Dimethyl Ether -- 8.8 Remarks -- References -- 9 Photochromic Reactions in Nanospace: Host-Guest Interactions and Opportunity -- 9.1 Introduction -- 9.2 Effects of the Confinements of Photochromic Molecules into MPSs on Photochromic Reactions -- 9.2.1 Azobenzene -- 9.3 Spiropyran and Spirooxazine -- 9.4 Preparation of Photochromic Hybrids Based on Mesoporous Silicas and Photochromic Dyes and Their Application -- 9.4.1 Drug Delivery -- 9.4.2 Photoinduced Adsorption -- 9.5 Photoinduced Molecular Migration -- 9.6 Conclusions and Future Perspectives -- Acknowledgments -- References -- 10 Dyes Encapsulated Within Porous Aluminosilicates as Photocatalysts -- 10.1 Introduction
- 10.1.1 Inorganic Photocatalysts -- 10.1.2 Organic Photocatalysts -- 10.2 Zeolites and Related Regular Porous Aluminosilicates -- 10.3 Incorporation Procedures -- 10.4 Modification of Photophysical Properties by Zeolite Encapsulation -- 10.5 Ruthenium(II) Trisbipyridyl [Ru(bpy)32+] Complex Encapsulated Inside Microporous Zeolites -- 10.6 Triphenylpyrylium ion Encapsulated Inside Zeolite Y -- 10.7 Phthalocyanines Encapsulated in Zeolites as Solid Singlet Oxygen Photosensitizers -- 10.8 Conclusions and Future Prospects -- References -- 11 Application of Plasmon-Assisted Photochemistry and Photocatalytic Activities to Zeolitic Media -- 11.1 Introduction -- 11.2 Basics of Plasmons -- 11.3 Plasmonic Photocatalysis -- 11.4 Application to Zeolitic Media -- 11.5 Future Perspective -- References -- Further Reading -- 12 Silica-Based Materials for Bioanalytical Chemistry and Optoelectronics -- 12.1 Introduction -- 12.2 Silica Nanostructures and Mesostructures -- 12.2.1 Ordered Mesoporous Materials -- 12.2.2 Ordered Zeolites -- 12.2.3 Amorphous Silica Nanostructures With Controllable Morphology -- 12.2.4 Ordered Silica Diatoms -- 12.3 Dye-Silica Conjugates -- 12.3.1 Photosynthesis Mimic -- 12.3.2 Silica-Based Sensors for Analytes -- 12.3.3 Biological and Biomedical Applications -- 12.4 Conclusion and Future Outlook -- Acknowledgment -- References -- Appendix -- 13 Dye Encapsulation Into One-Dimensional Zeolitic Materials for Optical Applications -- 13.1 Introduction -- 13.2 Antenna Systems -- 13.2.1 Antenna Systems Based on Förster Through-Space Mechanism Between Dyes Into Linde Type L Included by Diffusional Appr... -- 13.2.2 Antenna Systems Based on Dyes Occluded Into 1D Aluminophosphate by Crystallization Inclusion Approach (One-Pot Synth... -- 13.3 Other Optical Properties -- 13.4 Conclusion -- Acknowledgments -- References
- 14 Electron Transfers Under Confinement in Channel-Type Zeolites