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Polyaniline blends, composites, and nanocomposites
- Available as
- Online
Details
- Creator
- edited by P. M. Visakh, Cristina Della Pina, Ermelinda Falletta
- Format
- Books
- Language
- English
- Publication
-
- Amsterdam, Netherlands : Elsevier, 2018
- ©2018
- Physical Details
-
- 1 online resource (339 pages) : illustrations, tables
- ISBNs
- 9780128095515, 0128095512, 0128095660, 9780128095669
- OCLC
- on1008769101
- Includes bibliographical references at the end of each chapters and index.
- Front Cover -- Polyaniline Blends, Composites, and Nanocomposites -- Polyaniline Blends, Composites, and Nanocomposites -- Copyright -- Contents -- List of Contributors -- Preface -- 1 - Polyaniline-Based Blends, Composites, and Nanocomposites: State of the Art, New Challenges, and Opportunities -- 1.1 POLYANILINE: STRUCTURE AND PROPERTIES RELATIONSHIP -- 1.2 MODIFICATION OF POLYANILINE -- 1.3 POLYANILINE NANO-/MICROMATERIAL-BASED BLENDS AND COMPOSITES -- 1.4 POLYANILINE-BASED THERMOPLASTIC BLENDS -- 1.5 POLYANILINE-BASED BLENDS: NATURAL RUBBER AND SYNTHETIC RUBBER -- 1.6 POLYANILINE-BASED COMPOSITES AND NANOCOMPOSITES -- 1.7 CHARACTERIZATION OF POLYANILINE-BASED BLENDS, COMPOSITES, AND NANOCOMPOSITES -- 1.8 POLYANILINE-NATURAL POLYMER COMPOSITES AND NANOCOMPOSITES -- 1.9 APPLICATIONS OF POLYANILINE-BASED BLENDS, COMPOSITES, AND NANOCOMPOSITES -- 1.10 OTHER APPLICATIONS OF POLYANILINE-BASED BLENDS, COMPOSITES, AND NANOCOMPOSITES -- 1.11 POLYANILINE-NANOMATERIAL COMPOSITES: STRUCTURAL, OPTICAL, AND ELECTRICAL PROPERTIES -- REFERENCES -- 2 - Polyaniline: Structure and Properties Relationship -- 2.1 INTRODUCTION -- 2.2 STRUCTURE -- 2.3 POLYMERIZATION AND MANUFACTURE -- 2.3.1 OXIDATIVE CHEMICAL SYNTHESIS -- 2.3.2 INTERFACIAL POLYMERIZATION -- 2.3.3 MICROEMULSION POLYMERIZATION -- 2.3.4 SOLID-STATE SYNTHESIS -- 2.3.5 ELECTROCHEMICAL POLYMERIZATION -- 2.3.6 ELECTROSPINNING -- 2.3.7 ENZYMATIC SYNTHESIS -- 2.4 ADDITIVES -- 2.5 PROCESSING AND SUPPLIERS -- 2.6 APPLICATIONS -- 2.7 MORPHOLOGY -- 2.8 CRYSTAL STRUCTURE AND CRYSTALLIZATION BEHAVIOR -- 2.9 PHYSICAL PROPERTIES -- 2.10 MECHANICAL PROPERTIES -- 2.11 THERMAL PROPERTIES AND FLAMMABILITY -- 2.12 CHEMICAL PROPERTIES -- 2.13 ELECTRICAL AND OPTICAL PROPERTIES -- 2.14 WEATHERING AND RADIATION RESISTANCE -- 2.15 FUTURE AND ENVIRONMENTAL IMPACT -- 2.16 CONCLUSIONS -- REFERENCES
- 3 - Modification of Polyaniline -- 3.1 INTRODUCTION -- 3.2 GAMMA AND ELECTRON BEAM IRRADIATIONS -- 3.2.1 PRINCIPLE OF THE TECHNIQUES -- 3.2.2 EFFECTS OF IRRADIATION ON POLYANILINE -- 3.2.2.1 Cross-Linking -- 3.2.2.2 Microstructure -- 3.2.2.3 Mechanical and Wear Properties -- 3.2.2.4 Degradation and Oxidative Behavior -- 3.2.2.4.1 Theoretical Analysis of Oxidation Depth in a Polymer Film -- 3.2.3 STABILIZATION OF IRRADIATED POLYANILINE -- 3.2.4 SOLUBILITY OF IRRADIATED POLYANILINE -- 3.3 ION IMPLANTATION TECHNIQUE -- 3.3.1 PRINCIPLE OF THE TECHNIQUE -- 3.3.2 ION IMPLANTATION METHODS -- 3.3.2.1 Ion Implantation by Different Ions -- 3.3.2.2 Plasma Immersion Ion Implantation -- 3.3.3 ION IMPLANTATION SPECIES -- 3.3.4 EFFECTS AND USES OF THE ION IMPLANTATION ON POLYANILINE -- 3.3.4.1 Effect on Chemical Changes on Polyaniline -- 3.3.4.1.1 Effect on Concentration of Radical of Polyaniline -- 3.3.4.1.2 Effect on Amount of Nitrogen Atoms in Polyaniline -- 3.3.4.1.3 Effect of Concentration of Hydrogen Atoms in Polyaniline -- 3.3.4.2 Effect of Ion Implantation on Electrical Conductivity of Polyaniline -- 3.3.4.3 Effect on Stability of Polyaniline in the Environment -- 3.3.4.4 Effect on Shrinkage Effects and Color Change of Polyaniline -- 3.3.4.5 Oxidation-Reduction Effect of Polyaniline on Ion Implantation -- 3.3.4.6 Effect on Degradation of Polyaniline -- 3.4 CONCLUSIONS -- REFERENCES -- 4 - Polyaniline Nano-/Micromaterials-Based Blends and Composites -- 4.1 INTRODUCTION -- 4.2 POLYANILINE NANO-/MICROMATERIALS-BASED BLENDS -- 4.2.1 SOLUTION BLENDING METHOD -- 4.2.2 MELT BLENDING METHOD -- 4.3 POLYANILINE NANO-/MICROMATERIALS-BASED COMPOSITE -- 4.3.1 DISPERSION POLYMERIZATION METHOD -- 4.3.2 SONOCHEMICAL ROUTE -- 4.3.3 ELECTROCHEMICAL METHODS -- 4.3.4 IN SITU POLYMERIZATION TECHNIQUE -- 4.3.5 EMULSION POLYMERIZATION PATHWAY -- 4.4 CONCLUSIONS -- REFERENCES
- 5 - Polyaniline-Based Thermoplastic Blends -- 5.1 INTRODUCTION -- 5.2 PREPARATION -- 5.2.1 IN SITU POLYMERIZATION OF ANILINE IN A TP MATRIX -- 5.2.1.1 Emulsion Pathways -- 5.2.1.2 NP/PANI/TP Blends by In Situ Polymerization -- 5.2.2 EX SITU BLENDS -- 5.2.2.1 Melt Blends -- 5.2.2.1.1 Ternary Melt-Processed Blend -- 5.2.2.1.2 Melting Process With Ionic Liquid -- 5.2.2.2 Solution Casting Blends -- 5.2.3 ELECTROSPINNING -- 5.2.4 ELECTROCHEMICAL SYNTHESIS -- 5.3 PROPERTIES -- 5.3.1 MORPHOLOGY -- 5.3.2 TRANSPORT PROPERTIES -- 5.3.3 THERMOMECHANICAL PROPERTIES -- 5.3.4 RHEOLOGICAL PROPERTIES -- 5.4 APPLICATIONS -- 5.4.1 GAS SENSORS -- 5.4.2 WELDING OF PLASTICS -- 5.4.3 CORROSION PROTECTION -- 5.4.4 ELECTRONIC DEVICES -- 5.4.5 MEMBRANES -- 5.4.6 RADAR ABSORBING MATERIALS -- 5.5 CONCLUSIONS -- ABBREVIATIONS -- REFERENCES -- 6 - Polyaniline-Based Blends: Natural Rubber and Synthetic Rubber -- 6.1 INTRODUCTION -- 6.2 POLYANILINE-BASED NATURAL RUBBER BLENDS -- 6.2.1 POLYANILINE/NATURAL RUBBER COMPOSITE FIBERS -- 6.2.1.1 Preparation -- 6.2.1.2 Thermal Stability -- 6.2.1.3 Mechanical Properties -- 6.2.1.4 Electrical Conductivity -- 6.2.2 NATURAL RUBBER/POLYANILINE-DBSA COMPOSITE -- 6.2.2.1 Preparation -- 6.2.2.1.1 Synthesis of PANI-DBSA -- 6.2.2.1.2 Preparation of NR/PANI-DBSA Composite -- 6.2.2.2 Thermal Properties -- 6.2.2.3 Stress-Strain Properties -- 6.2.2.4 Applications -- 6.2.3 PANI BLEND WITH ENR-50 -- 6.2.3.1 Preparation -- 6.2.3.1.1 Preparation of ENR-50/PANI.DBSA Composites -- 6.2.3.2 Properties -- 6.2.3.3 Nanomechanical Properties -- 6.2.3.4 Applications -- 6.2.4 POLYANILINE-COATED SHORT NYLON FIBER/NATURAL RUBBER -- 6.2.4.1 Preparation of Polyaniline -- 6.2.4.1.1 Preparation of Polyaniline-Coated Short Nylon-6 Fiber -- 6.2.4.1.2 Composite Preparation -- 6.2.4.2 Mechanical Properties -- 6.2.4.3 Electrical Conductivity -- 6.2.4.4 Thermal Characteristics
- 6.2.4.5 Applications -- 6.3 POLYANILINE-BASED SYNTHETIC RUBBER BLENDS -- 6.3.1 POLYANILINE BLEND WITH NITRILE RUBBER -- 6.3.1.1 Preparation -- 6.3.1.2 Surface and Volumetric Conductivity -- 6.3.1.3 Mechanical Properties -- 6.3.1.4 Applications -- 6.3.2 POLYANILINE-COATED NYLON FIBER AND CHLOROPRENE RUBBER -- 6.3.2.1 Preparation -- 6.3.2.2 Stress-Strain Properties -- 6.3.2.3 Thermal Characteristics -- 6.3.3 POLYANILINE/ORGANOCLAY NANOCOMPOSITE AND EPDM RUBBER -- 6.3.3.1 Preparation of PANI-DBSA/Organoclay Nanocomposites -- 6.3.3.2 Preparation of PANI-DBSA/Organoclay-EPDM Composites -- 6.3.3.3 Electrical Properties -- 6.3.3.4 Thermal Properties -- 6.3.3.5 Stress-Strain Properties -- 6.3.3.6 Applications -- 6.3.4 POLYANILINE/ETHYLENE PROPYLENE DIENE RUBBER BLENDS -- 6.3.4.1 Preparation -- 6.3.4.1.1 PANI(DBSA) Complex Preparation -- 6.3.4.1.2 Blend Preparation -- 6.3.4.2 Thermal Properties -- 6.3.4.3 Applications -- 6.3.5 SBS BLOCK COPOLYMER-POLYANILINE BLENDS -- 6.3.5.1 Synthesis of Polyaniline Doped with DBSA -- 6.3.5.2 Electrical Conductivity -- 6.3.5.3 Mechanical Properties -- 6.3.5.4 Applications -- 6.4 CONCLUSION -- REFERENCES -- 7 - Polyaniline-Based Composites and Nanocomposites -- 7.1 POLYANILINE-TIO2 NANOCOMPOSITES -- 7.1.1 NANOTUBES -- 7.1.2 NANOPARTICLES -- 7.1.3 NANOWIRES -- 7.1.4 NANORODS -- 7.1.5 NANOSHEETS -- 7.2 POLYANILINE-CALCIUM CARBONATE COMPOSITES -- 7.3 NATURAL FIBER-BASED POLYANILINE COMPOSITES -- 7.4 FILLER-BASED POLYANILINE COMPOSITES -- 7.5 POLYANILINE-SILICA NANOCOMPOSITES -- 7.6 POLYANILINE-CLAY NANOCOMPOSITES -- 7.7 POLYANILINE-MANGANESE DIOXIDE NANOCOMPOSITES -- 7.8 POLYANILINE-POROUS CARBON COMPOSITES -- 7.9 POLYANILINE-COPPER NANOCOMPOSITES -- 7.10 POLYANILINE-MONTMORILLONITE NANOCOMPOSITES -- 7.11 POLYANILINE-GRAPHENE NANOCOMPOSITES -- 7.12 CELLULOSE WHISKERS-POLYANILINE NANOCOMPOSITES -- 7.13 CONCLUSIONS -- REFERENCES
- 8 - Characterization of Polyaniline-Based Blends, Composites, and Nanocomposites -- 8.1 INTRODUCTION -- 8.2 MECHANICAL PROPERTIES -- 8.3 DYNAMIC MECHANICAL ANALYSIS -- 8.4 THERMOGRAVIMETRIC ANALYSIS -- 8.5 DIFFERENTIAL SCANNING CALORIMETRY -- 8.6 SCANNING ELECTRON MICROSCOPY -- 8.7 ATOMIC FORCE MICROSCOPY -- 8.8 TRANSMISSION ELECTRON MICROSCOPY -- 8.9 X-RAY DIFFRACTION -- 8.10 SMALL ANGLE X-RAY SCATTERING ANALYSIS -- 8.11 CONCLUSIONS -- REFERENCES -- 9 - Polyaniline/Natural Polymer Composites and Nanocomposites -- 9.1 INTRODUCTION -- 9.2 POLYANILINE/CELLULOSE-BASED COMPOSITES AND NANOCOMPOSITES -- 9.2.1 CELLULOSE -- 9.2.2 POLYANILINE/CELLULOSE COMPOSITES -- 9.2.3 POLYANILINE/BACTERIAL CELLULOSE NANOCOMPOSITE -- 9.2.4 POLYANILINE/MODIFIED CELLULOSE COMPOSITES -- 9.2.4.1 Polyaniline/Ethyl Cellulose Composites -- 9.2.4.2 Polyaniline/Carboxymethyl Cellulose Composites -- 9.2.4.3 Polyaniline/Cellulose Triacetate Composite -- 9.2.4.4 Polyaniline/Cellulose Ester Membranes -- 9.3 POLYANILINE/CHITIN-BASED COMPOSITES AND NANOCOMPOSITES -- 9.3.1 CHITIN -- 9.3.1.1 Isolation of Chitin -- 9.3.1.2 Drawbacks of Chitin -- 9.3.2 CHITIN-POLYANILINE COMPOSITES -- 9.3.3 CHITOSAN -- 9.3.4 CHITOSAN/POLYANILINE COMPOSITES -- 9.3.5 APPLICATIONS OF CHITOSAN-POLYANILINE COMPOSITES -- 9.3.5.1 Pervaporation -- 9.3.5.2 Artificial Muscles -- 9.3.5.3 Metal Ion Sorption -- 9.3.5.4 Dye Adsorption -- 9.3.5.5 Biosensor -- 9.3.5.6 Gas Sensor -- 9.3.6 CHITOSAN-METAL OXIDE/POLYANILINE COMPOSITES -- 9.3.6.1 Formation Mechanism of Chitosan-ZnO/Polyaniline Hybrid Composites -- 9.3.6.2 Antimicrobial Activity -- 9.4 POLYANILINE/STARCH-BASED COMPOSITES AND NANOCOMPOSITES -- 9.4.1 ADVANTAGES OF STARCH/POLYANILINE COMPOSITE -- 9.5 POLYANILINE/SEAWEED-BASED COMPOSITES AND NANOCOMPOSITES -- 9.6 POLYANILINE/OTHER NATURAL POLYMER-BASED COMPOSITES AND NANOCOMPOSITES -- 9.7 CONCLUSIONS -- REFERENCES
- 10 - Applications of Polyaniline-Based Blends, Composites, and Nanocomposites