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Advances in organometallic chemistry Volume 60
- Available as
- Online
- Summary
-
Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains author...
Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field that has expanded enormously since the publication of Volume 1 in 1964. Key features: * Contributions from leading authorities * Informs and updates on all the latest developments in the field
Details
- Creator
- edited by Anthony F. Hill, Mark J. Fink ; founding editors, F. Gordon A. Stone, Robert West
- Format
- Books
- Language
- English
- Contributors
- Publication
-
- 1st ed
- Amsterdam ; Boston : Elsevier/Academic Press, 2012
- Physical Details
-
- 1 online resource (193 p.)
- ISBNs
- 9780123969705, 0123972779, 1283835657, 0123969700, 9781283835657, 9780123972774
- OCLC
- ocn823729323, ocn823388756
- Description based upon print version of record.
- Includes bibliographical references and index.
- English
- Front Cover; Advances in Organometallic Chemistry; Copyright; Contents; Contributors; Chapter One: Homogeneous Organometallic Chemistry of Methane; 1. Introduction; 2. Inspiration: The Early Days of Hydrocarbon Activation; 3. Oxidative Addition; 3.1. Controlled oxidative addition; 3.2. Alkane dehydrogenation; 4. σ-Bond Metathesis; 5. 1,2-Addition; 6. Metalloradicals; 7. 1,3-Addition; 8. Electrophilic Carbene Insertion; 9. Conclusions; References; Chapter Two: Supramolecular Self-assembly of Transition Metal Carbonyl Molecules Through M-CO(Lone Pair). . . π(Arene) Interactions; 1. Introduction
- 2. Data Mining3. Supramolecular Aggregation Based on M-CO(Lone Pair). . .π(Arene) Interactions; 3.1. Motif A; 3.2. Motif B; 3.3. Motif C; 3.4. Motif D; 3.5. Motifs E, F, and G; 3.6. Motifs H and I; 3.7. Motif J; 3.8. Motif K; 4. Thio- and Selenocarbonyl Analogues; 5. Strength and Correlations; 6. Conclusions and Outlook; Acknowledgments; References; Chapter Three: Metallabenzenes and Metallabenzenoids; 1. Introduction; 2. Synthetic Routes to Metallabenzenes and Metallabenzenoids; 2.1. Metallacyclic ring expansion or contraction
- 2.1.1. Ring expansion of metallacyclopentadienes through insertion of one carbon atom2.1.1.1. Migratory insertion involving a vinylidene ligand and a metallacyclopentadiene; 2.1.1.2. Migratory insertion involving a carbene ligand and a metallacyclopentadiene; 2.1.1.3. Migratory insertion involving a carbyne ligand and a metallacyclopentadiene; 2.1.1.4. Migratory insertion involving a thiocarbonyl ligand and a metallacyclopentadiene; 2.1.1.5. Migratory insertion involving a carbonyl ligand and a metallacyclopentadiene
- 2.1.2. Ring expansion of metallacyclobutenethiones or metallacyclobutadienes through insertion of two carbon atoms2.1.2.1. Migratory insertion involving an ethyne and a metallacyclobutenethione; 2.1.2.2. Migratory insertion involving an alkyne and a metallacyclobutadiene; 2.1.3. Ring contraction of metallacycloheptatrienes; 2.2. Addition to a metal substrate of a molecule or anion that contains the five carbon atoms of the impending metallabenzene; 2.2.1. Reactions with the 2,4-dimethylpentadienide anion; 2.2.2. Reactions with lithiated Z-3-(2-iodoethenyl)cyclopropenes
- 2.2.3. Reactions with 1,4-pentadiyne-3-ol and related compounds2.2.3.1. Reactions with 1,4-pentadiyne-3-ol; 2.2.3.2. Reactions with pent-1-en-4-yn-3-ols; 2.2.3.3. Reactions with 1-phenylprop-2-yn-1-ol; 2.3. Modification of six-membered metallacyclic rings; 2.3.1. Reaction of osmabenzynes with nucleophiles; 2.3.2. Modification of metallacyclohexadienes; 2.4. Intramolecular coupling of the δ-carbon of one ligand with the carbon donor of an adjacent ligand; 2.4.1. Coupling of CO with the lithiated δ-carbon atom of an adjacent ligand
- 2.4.2. Coupling of vinylidene with the δ-carbon atom of a butadienyl ligand