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Advances in organobromine chemistry II proceedings, ORGABROM '93, Jerusalem, June 28-July 2, 1993
- Author / Creator
- Conferences
- ORGABROM '93 (1993 : Jerusalem)
- ORGABROM '93
- Available as
- Online
- Summary
-
The organic molecules that are used, particularly in the areas of pharmacy and agrochemicals, are becoming more and more complex both in their chemical nature and spacial configuration. A complex m...
The organic molecules that are used, particularly in the areas of pharmacy and agrochemicals, are becoming more and more complex both in their chemical nature and spacial configuration. A complex molecular structure is inevitably fragile; it cannot be produced under severe conditions (in particular high pressure and temperature). In addition there is a problem of the scale-up of a product from the laboratory to the industrial scale. The control of the reactivity, selectivity, and yield and the use of sufficiently mild industrial conditions are all factors that must be taken into account by ind
Details
- Creator
- edited by Jean-Roger Desmurs, Bernard Gérard, Melvin J. Goldstein
- Format
- Books
- Language
- English
- Contributors
- Publication
-
- Amsterdam ; New York : Elsevier, 1995
- Physical Details
-
- 1 online resource (441 p.)
- ISBNs
- 9780080544649, 9786611055264, 9780444821058, 0444821058, 1281055263, 0080544649
- OCLC
- ocn648350943, ocn162130761
- Description based upon print version of record.
- Includes bibliographical references and indexes.
- English
- Cover; Contents; Preface; Acknowledgements; Organizing Committee; Scientific Committee; INTRODUCTION; PART I: PREPARATION OF ORGANOBROMINATED COMPOUNDS SYNTHESIS; Chapter 1. Regioselective bromination of phenols; Chapter 2. Bromination of aromatic compounds with alumina-supported copper (II) bromides; Chapter 3. Bromination and oxidation with benzyltrimethyl ammonium tribromide; Chapter 4. Advances in the synthesis and applications of organobromine compounds; Chapter 5. High temperature bromination IV. Bromination of benzonorbornadiene and benzobarrelene
- Chapter 6. Bromination of ergolene and ergoline structures New resultsChapter 7. Thermal rearrangement of hexabromocyclododecane; PART II: PREPARATION OF ORGANOBROMINATED COMPOUNDS REACTION MECHANISMS; Chapter 8. Stereo-, regio- and chemoselectivity of bromination of ethylenic compounds; Chapter 9. The Fates of bromonium ions in solution : a very short lifetime with many different endings; Chapter 10. New mechanistic insight into the electrophilic bromination of olefins; PART III: USE OF ORGANOBROMINATED COMPOUNDS SYNTHESIS; Chapter 11. Synthesis of a metabolite of fantofarone
- Chapter 12. 2-Bromoamides. Stereocomrolled substitution and application to the synthesis of compounds of biological interestChapter 13. Asymmetric synthesis of (S)-a-substituted ß-bromo-a-hydroxy acids; Chapter 14. Substrate specific reactions of dibromides of a-arylidene-benzocyclanones with azide nucleophile; Chapter 15. Organobromine compounds in reactions of homolytic addition and telomerization; Chapter 16. Bromides in zeolite synthesis / Zeolites in bromide synthesis and conversion
- Chapter 17. An improved synthesis of biaryl derivatives via the palladium catalyzed coupling of aryl bromidesPART IV: USE OF ORGANOBROMINATED COMPOUNDS REACTION MECHANISM; Chapter 18. Kinetics and mechanism of decomposition of N-Br-amino acids in alkaline medium; Chapter 19. Arylation of hard heteroatomic nucleophiles using bromoarenes substrates and Cu, Ni, Pd-catalysts; Chapter 20. Hydrogen bromide elimination from diastereomeric 3-bromoflavanones Mechanistic aspects; Chapter 21. Bromide-mediated oxidations of organic compounds; PART V: INDUSTRIAL ASPECTS
- Chapter 22. New catalytic process for bromine recoveryChapter 23. Bromine chloride production: study in a reaction calorimeter; Chapter 24. Influence of bromine containing fire retardants on the processing and properties of plastics; Chapter 25. Phosphorus-bromine flame retardant synergy in engineering thermoplastics; PART VI: ENVIRONMENT; Chapter 26. Treatment of bromide effluent problems with H2O2 technology; Chapter 27. Behavior and fate of aromatic bromine compounds in the environment; PART VII: TOXICOLOGY
- Chapter 28. Comparison of hepatotoxicity of monobromo benzenes, dibromobenzenes, hexabromobenzenes and tetrabromobisphenol A